Physico-mechanical and microstructural properties of geopolymers under the influence of different sulphates
DOI:
https://doi.org/10.7764/RDLC.25.1.193Keywords:
Geopolymer, durability, compressive strength, sodium sulfate, magnesium sulfate.Abstract
To contribute to sustainable environmental protection studies, the durability and strength properties of geopolymer, which is known as more eco- friendly than ordinary Portland cement, have been a phenomenon among many researchers in recent years. In this study, the durability properties of geopolymer mortars containing C Class fly ash (FA) added with silica fume (SF) were investigated under the influence of sodium sulfate (NS) and magnesium sulfate (MS). Within the scope of the study, FA geopolymer mortar samples were produced with fixed ratios of potassium hydroxide (KOH) and sodium hydroxide (NaOH) and 3 different ratios of silica fume additive (5%, 10%, 15%). The samples were kept at room temperature for up to 28 days after production. Their physic-mechanical properties were examined. The samples were placed in NS and MS solution. Length and weight changes, flexural and compressive strengths of the samples were measured for 30 days, 90 days and 180 days. As a result of the experiments, it was observed that the samples produced by activating with NaOH didn’t lose strength at a high ratio, while the compressive strength (CS) of the samples produced by activating with KOH and under the influence of sulfate increased on the 30th day. It was determined that the CS of the samples under the influence of NS reached 75.14 MPa at 30 curing days and the samples under the influence of MS reached 64.31 MPa. In general, the produced samples were found to be resistant to sulfate effects.
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References
Aiken, T., Kwasny, J., Sha, W. and Soutsos, M., (2013). Effect of slag content and activator dosage on the resistance of fly ash geopolymer binders to sulfuric acid attack. Cement and Concrete Research, Cilt 111, p. 23–40.
Albitar, M., Mohamed Sadakkathulla, M., Visintin, P., Lavigne, O., Gamboa, E. (2016). Bond Slip Models for Uncorroded and Corroded Steel Reinforce-ment in Class-F Fly Ash Geopolymer Concrete. Journal of Materials in Civil Engineering, Cilt 29.
Ariffin, M. A. M., Bhutta, M. A. R., Hussin, M. W., Tahir, M. M., and Aziah, N. (2013). Sulfuric acid resistance of blended ash geopolymer concrete. Con-struction and building materials. . 80–86.
Assi, L. Carter, K., Deaver, E. E., Anay, R., and Ziehl, P. (2018). Sustainable concrete: Building a greener future. Journal of cleaner production, 198, 1641-1651.
ASTM/C642-21, 2022. Standard Test Method for Density, Absorption, and Voids in Hardened Concrete.
ASTM-C1012/C1012M-12, 2013. Standard Test Method for Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution.
ASTM-C618-5, 2010. Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete.
Atabey, İ., (2017). Investigation of durability properties of F class fly ash geopolymer mortar, Kayseri.
Atabey, İ., Karahan, O., Bilim, C. and Atiş, C., (2020). The influence of activator type and quantity on the transport properties of class F fly ash geopoly-mer. Construction and Building Materials, December, 264, 120268.
Atabey, İ., Karahan, O., Bilim, C. and Atiş, C., (2020b). Very high strength Na2SiO3 and NaOH activated fly ash based geopolymer mortar. Cement Wapno Beton, 25, 292–305.
Atiş, C. D., Görür, E. B., Karahan, O. K. A. N., Bilim, C., İlkentapar, S., and Luga, E. (2015). Very high strength (120MPa) class F fly ash geopolymer mortar activated at different NaOH amount, heat curing temperature and heat curing duration. Construction and Building Materials, 96, 673–678.
Aygörmez, Y., (2021). Performance of ambient and freezing-thawing cured metazeolite and slag based geopolymer composites against elevated tempera-tures. Revista de la construcción, 20,145–162.
Aygörmez, Y. (2023). Sulfate and chloride resistance of bottom ASH doped slag-based geopolymer composites. Sigma Journal of Engineering and Natural Sciences, 41(2), 288-301
Aygörmez, Y., Canpolat, O., Al-Mashhadani, M. and Uysal, M., (2020). Elevated temperature, freezing-thawing and wetting-drying effects on polypropyl-ene fiber reinforced metakaolin based geopolymer composites. Construction and Building Materials, 235,117502.
Bajpai, R., Choudhary, K., Srivastava, A., Sangwan, K. S., and Singh, M. (2020). Environmental impact assessment of fly ash and silica fume based geopolymer concrete. Journal of Cleaner Production, 254, 120147.
Bakharev, T., (2005). Durability of geopolymer materials in sodium and magnesium sulfate solutions. Cement and Concrete Research. 5,1233–1246.
Banu, S., J., Kumutha, R., Vijai, K. (2017). A review on durability studies of geopolymer concrete and mortar under aggressive environment. SSRG Inter-national Journal of Civil Engineering 4(5), 32-35.,
Bell, J., Gordon, M. and Kriven, W., (2005). Use of Geopolymeric Cements as a Refractory Adhesive for Metal and Ceramic Joins. basım yeri bilinmiyor, John Wiley and Sons, Inc., p. 407–413.
Beltrame, N., Luz, C. A. D., Perardt, M. and Hooton, R., (2020). Alkali activated cement made from blast furnace slag generated by charcoal: Resistance to attack by sodium and magnesium sulfates. Construction and Building Materials. 238, 117710.
Benhelal, E., Zahedi, G., Shamsaei, E. and Bahadori, A., (2013). Global strategies and potentials to curb CO2 emissions in cement industry. Journal of Cleaner Production, 51,142–161.
Chen, S. ve diğerleri, (2020). The influence of Si/Al ratio on sulfate durability of metakaolin-based geopolymer. Construction and Building Materials. 265, 120735.
Chindaprasirt, P., Rattanasak, U. and Jaturapitakkul, C., (2011). Utilization of fly ash blends from pulverized coal and fluidized bed combustions in geopolymeric materials. Cement and Concrete Composites.33. 55–60
Chindaprasirt, P., Silva, P. D., Sagoe-Crentsil, K. and Hanjitsuwan, S., (2012). Effect of SiO2 and Al2O3 on the setting and hardening of high calcium fly ash-based geopolymer systems. Journal of Materials Science. 47, 4876–4883.
Chindaprasirt, P., Thaiwitcharoen, S., Kaewpirom, S., Rattanasak, U. (2013). Controlling ettringite formation in FBC fy ash geopolymer con-crete. Cement and Concrete Composites, 41:24–32.
Chitsaz, S. and Tarighat, A., (2021). Estimation of the modulus of elasticity of N-A-S-H and slag-based geopolymer structures containing calcium and magnesium ions as impurities using molecular dynamiCS simulations. CeramiCS International. 47, 6424–6433.
Davidovits, J., (1991). Geopolymers: inorganic polymeric new materials. Journal of Thermal Analysis and calorimetry. Journal of Thermal Analysis, 37, 1633–1656.
Deep, A., and Sarkar, P. (2025). Durability of copper slag aggregate geopolymer concrete exposed to acid and sulphate attack. Construction and Building Materials, 493, 143107.
Downs, B. and Yang, H., (2021). RRUFF Project website . https://rruf. info/Ettringite. Accessed 11 Jun 2024.
Durgun, M. Y., and Sevinç, A. H. (2022). Determination of the effectiveness of various mineral additives against sodium and magnesium sulfate attack in concrete by Taguchi method. Journal of Building Engineering, 57, 104849.
Duxson, P., Lukey, G. and Deventer, J. V., (2006). Thermal Conductivity of Metakaolin Geopolymers Used as a First Approximation for Determining Gel Interconnectivity. Industrial andamp; Engineering Chemistry Research. 45,7781–7788.
Elyamany, H., Elmoaty, A. A. and Elshaboury, A., (2018). Magnesium sulfate resistance of geopolymer mortar. Construction and Building Materials. 184, 111–127.
Eser, A., Bayer Ozturk, Z., Atabey, İ. İ., and Çelikten, S. (2024). Mechanical properties of geopolymer mortars produced with fly ash and various ceramic industry wastes. Nigde Omer Halisdemir University J Engineering Sci, 13, 550-557.
Ferraris, C. and Wittmann, F. (1997). Shrinkage mechanisms of hardened cement paste. Cement and Concrete Research 17,453–464.
Galiano, L., Pereira, Y. F., Izquierdo, C. and M, (2016). Contributions to the study of porosity in fly ash-based geopolymers. Relationship between degree of reaction, porosity and compressive strength. Materiales de construcción, p. 66.
Ganeshan, M. and Venkataraman, S., (2021). Durability and microstructural studies on fly ash blended self-compacting geopolymer concrete. European Journal of Environmental and Civil Engineering, 25, 2074–2088.
García-Lodeiro, I., Palomo, A. and Fernández-Jiménez, A. (2007). Alkali–aggregate reaction in activated fly ash systems. Cement and Concrete Research. 37, 175–183.
García-Lodeiro, I., Palomo, A., Fernández-Jiménez, A., and Macphee, D. E. (2011). Compatibility studies between NASH and CASH gels. Study in the ternary diagram Na2O–CaO–Al2O3–SiO2–H2O. Cement and Concrete Research, 41(9), 923-931.
Geckil, T., Sarici, T., and Aksoy, H. S. (2025). The usability of construction and demolition wastes stabilized using alkali activated fly ash as filler material. Revista de la construcción, 24(2), 428-448.
Gong, K. and White, C., (2018). Nanoscale Chemical Degradation Mechanisms of Sulfate Attack in Alkali-activated Slag. The Journal of Physical Chem-istry 122(11), 5992–6004.
Gopalakrishnan, R. and Chinnaraju, K., (2019). Durability of ambient cured alumina silicate concrete based on slag/fly ash blends against sulfate envi-ronment. Construction and Building Materials, 204, 70–83.
Gupta, P., Nagpal, G. and Gupta, N., (2021). Fly ash-based geopolymers: an emerging sustainable solution for heavy metal remediation from aqueous medium. Beni-Suef University Journal of Basic and Applied Sciences. 10, 89.
Hasnaoui, A., Ghorbel, E. and Wardeh, G., (2019). Optimization approach of granulated blast furnace slag and metakaolin based geopolymer mortars. Construction and Building Materials, 198, 10–26.
He, W., Li, B., Meng, X. and Shen, Q. (2023). Compound Effects of Sodium Chloride and Gypsum on the Compressive Strength and Sulfate Resistance of Slag-Based Geopolymer Concrete. Buildings. 13, 675.
I Inada, M., Tsujimoto, H., Eguchi, Y., Enomoto, N., Hojo, J. (2005). Microwave-assisted zeolite synthesis from coal fly ash in hydrothermal process. Fuel, 84,1482–1486.
Ismail, I., Bernal, S. A., Provis, J. L., Hamdan, S., and van Deventer, J. S. (2013). Microstructural changes in alkali activated fly ash/slag geopolymers with sulfate exposure. Materials and Structures. C46, 361–373.
Jena, S., Panigrahi, R. and Sahu, P. (2019). Mechanical and Durability Properties of Fly Ash Geopolymer Concrete with Silica Fume. Journal of The Insti-tution of Engineers (India): Series A, 13 100, p. 697–705.
Jiao, Z., Li, X., Yu, Q., Yao, Q., and Hu, P. (2023).. Sulfate resistance of class C/class F fly ash geopolymers. Journal of Materials Research and Technolo-gy, 23, 1767–1780.
Júnior, N. S. A., Neto, J. S. A., Santana, H. A., Cilla, M. S., and Ribeiro, D. V. (2021). Durability and service life analysis of metakaolin-based geopolymer concretes with respect to chloride penetration using chloride migration test and corrosion potential. Construction and Building Materials, 287, 122970.
Karakoc, M. B., Türkmen, İ., Maraş, M. M., Kantarci, F., and Demirboğa, R. (2016). Sulfate resistance of ferrochrome slag based geopolymer concrete. CeramiCS International. 42, 1254–1260.
Kaya, M., 2016. Examination of Mechanical and Durability Properties of Various Types of Fly Ash Produced by Using Alkali Activated Mortars Sakarya University, The Graudate School of Naturel and Applied Science. Civil Engineering Department.
Kaya, M., Köksal, F., Nodehi, M., Bayram, M., Gencel, O., and Ozbakkaloglu, T. (2022). The Effect of Sodium and Magnesium Sulfate on Physico-Mechanical and Microstructural Properties of Kaolin and Ceramic Powder-Based Geopolymer Mortar. Sustainability, 14(20), 13496.
Kaya, M., Uysal, M., Yilmaz, K. and Atis, C., (2018). Behaviour of Geopolymer Mortars after Exposure to Elevated Temperatures. Materials Science. 24, 428–436.
Kaya, M., Uysal, M., Yilmz, K., Karahan, O., Atis, C. D. (2020) Mechanical properties of class C and F fly ash geopolymer mortars. Journal of the Croa-tian Association of Civil Engineers.72, 97–309.
Khan, M., Kayali, O. and Troitzsch, U., (2017). Effect of NaOH activation on sulphate resistance of GGBFS and binary blend pastes. Cement and Con-crete Composites. 81, 49–58.
Khater, H. and Elnagar, A., (2013). Evaluation of chloride resistance of silica fume and glass waste MWCNT- geopolymer composite. International Jour-nal of Advanced Structural Engineering, 5, 131629.
Khater, H. and El-Nagar, A., (2020). Preparation of sustainable of eco-friendly MWCNT-geopolymer composites with superior sulfate resistance. Ad-vanced Composites and Hybrid Materials.3, 375–389.
Koç, H., (2021). Investigation of phsical and mechanical properties of alkali aktivated mortars produced with silica fume additive fly ash under the effect of different sulphates. Yozgat Bozok University, Postgraduate education institute, Civil Engineering Department.,
Komljenović, M., Baščarević, Z. and Bradić, V., (2010). Mechanical and microstructural properties of alkali-activated fly ash geopolymers. Journal of Hazardous Materials.181, 35–42.
Kong, D. and Sanjayan, J. (2010). Effect of elevated temperatures on geopolymer paste, mortar and concrete. Cement and Concrete Research, February, 40,334–339.
Kuri, J., Nuruzzaman, M. and Sarker, P., (2023). Sodium sulphate resistance of geopolymer mortar produced using ground ferronickel slag with fly ash. CeramiCS International, January, 49, 765–2773.
Kwasny, J., Aiken, T. A., Soutsos, M. N., McIntosh, J. A., and Cleland, D. J. (2018). Sulfate and acid resistance of lithomarge-based geopolymer mortars. Construction and Building Materials, 166, 537–553.
Liang, G., Zhu, H., Li, H., Liu, T., and Guo, H. (2021). Comparative study on the effects of rice husk ash and silica fume on the freezing resistance of metakaolin-based geopolymer. Construction and Building Materials, 293, 123486.
Li, Q., Xu, H., Li, F., Li, P., Shen, L., and Zhai, J. (2012). Synthesis of geopolymer composites from blends of CFBC fly and bottom ashes. Fuel, 97, 366-372.
Li, J., Song, K., Tao, Y., Cao, W., Wang, Y., & Yi, C. (2025). Production and optimization of sustainable, economical and sulphate-resistant binary geopol-ymers with a large sugarcane bagasse ash addition. Construction and Building Materials, 467, 140368.
Lv, Q. F., Wang, Z. S., Gu, L. Y., Chen, Y., and Shan, X. K. (2020). Effect of sodium sulfate on strength and microstructure of alkali-activated fly ash based geopolymer. Journal of Central South University, 27, 1691–1702.
Marchand, J., Older, I., Skalny, J.P.(2003). Sulfate Attack on Concrete, CRC Press,232
Mathew, B., Sudhakar, M. and Natarajan, C., (2013). Strength, economic and sustainability characteristiCS of coal ash-GGBS based geopolymer con-crete. International Journal Of Computational Engineering Research. 3, 207–212.
McLellan, B. C., Williams, R. P., Lay, J., Van Riessen, A., and Corder, G. D. (2011). Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement. Journal of Cleaner Production.19, 1080–1090.
Mehta, P.K., Monteiro, P.J.M. (2006) Concrete: Microstructure, Properties, and Materials, third ed., McGraw-Hill, New York, USA, p. 659.
Miranda, J., Fernández-Jiménez, A., González, J. and Palomo, A., 2005. Corrosion resistance in activated fly ash mortars. Cement and Concrete Research. 35, 210–1217.
Ozturk, Z. B., and Atabey, I. I. (2022). Mechanical and microstructural characteristiCS of geopolymer mortars at high temperatures produced with ceram-ic sanitaryware waste. CeramiCS International, 48(9), 12932-12944.
Parthiban, K., and Mohan, K. S. R. (2017). Influence of recycled concrete aggregates on the engineering and durability properties of alkali activated slag concrete. Construction and Building Materials, 133, 65-72.
Pouhet, R. and Cyr, M., (2016). Carbonation in the pore solution of metakaolin-based geopolymer. Cement and Concrete Research.88,,227–235.
Rangarao, M. and Pradhan, B., (2022). Effect of chloride and blend of chloride and sulphate salts on workability, early strength and microstructure of FA-GGBS geopolymer concrete. Materials Today: Proceedings.65,3907–3911.
Rashad, A. M., Bai, Y., Basheer, P. A. M., Milestone, N. B., and Collier, N. C. (2013). Hydration and properties of sodium sulfate activated slag. Cement and concrete composites, 37, 20-29.
Rees, C., Provis, J., Lukey, G. and Deventer, J. V., (2007). In Situ ATR-FTIR Study of the Early Stages of Fly Ash Geopolymer Gel Formation. Langmuir. 23, 9076–9082.
Ren, D., Yan, C., Duan, P., Zhang, Z., Li, L., and Yan, Z. (2017). Durability performances of wollastonite, tremolite and basalt fiber-reinforced metakaolin geopolymer composites under sulfate and chloride attack. Construction and Building Materials, March, Cilt 134, p. 56–66.
RILEM TC 211 – PAE, in: M. Alexander, A. Bertron, N. De Belie (Eds.), Performance of Cement-Based Materials in Aggressive Aqueous Environments, State-of-the-Art Report, RILEM TC 211 – PAE, vol.10, 2013, 462
Sara, J., Kumutha, R. and Vijai, K., (2017). A Review on Durability Studies of Geopolymer Concrete and Mortar under Aggressive Environment. Interna-tional Journal of Civil Engineering, 4, 32–35.
Sata, V., Sathonsaowaphak, A. and Chindaprasirt, P., (2012). Resistance of lignite bottom ash geopolymer mortar to sulfate and sulfuric acid attack. Cement and Concrete Composites.34, 700–708.
Sharma, U., Khatri, A. and Kanoungo, A. (2014). Use of micro-silica as additive to concrete-state of art. International Journal of Civil Engineering Re-search, 5, 9–12.
Shi, X., Feng, Y., Zhang, Y., and Su, Y. (2023). A comprehensive investigation on sulphate resistance of geopolymer recycled concrete: Macro and micro properties. Construction and Building Materials, 403, 133052.
Silva, I., Castro-Gomes, J. and Albuquerque, A., (2012). Effect of immersion in water partially alkali-activated materials obtained of tungsten mine waste mud. Construction and Building Materials.3 5, 117–124.
Singh, R. P., Vanapalli, K. R., Jadda, K., and Mohanty, B. (2024). Durability assessment of fly ash, GGBS, and silica fume based geopolymer concrete with recycled aggregates against acid and sulfate attack. Journal of Building Engineering, 82, 108354
Somna, K., Jaturapitakkul, C., Kajitvichyanukul, P. and Chindaprasirt, P., (2011). NaOH-activated ground fly ash geopolymer cured at ambient tempera-ture. Fuel. 90, 2118–2124.
Song, W., Guo, T., Han, P., Wang, X., Ma, F., and He, B. (2023). Durability study and mechanism analysis of red mud-coal metakaolin geopolymer con-crete under a sulfate environment. Construction and Building Materials, 409, 133990.
Supit, S. and Olivia, M., (2022). Compressive strength and sulfate resistance of metakaolin-based geopolymer mortar with different ratio of alkaline activator. Materials Today: Proceedings. 66, 776–2779.
Taylor, H. F. W., and Gollop, R. S. (1997). 21 some chemical and microstructural aspects of concrete durability. Mechanisms of chemical degradation of cement-based systems, 177-184
Tchakouté, H. and Rüscher, C., (2017). Mechanical and microstructural properties of metakaolin-based geopolymer cements from sodium waterglass and phosphoric acid solution as hardeners: A comparative study. Applied Clay Science.140,81–87.
Thaarrini, J. and Venkatasubramani, R., (2016). Feasibility Studies on Compressive Strength of Ground Coal Ash Geopolymer Mortar. Periodica Poly-technica Civil Engineering. 59, 373–379.
Timakul, P., Rattanaprasit, W. and Aungkavattana, P. (2016). Improving compressive strength of fly ash-based geopolymer composites by basalt fibers addition. CeramiCS International. 42, 6288–6295.
Tixier, R. and Mobasher, B., (2003). Modeling of Damage in Cement-Based Materials Subjected to External Sulfate Attack. I: Formulation. Journal of Materials in Civil Engineering.15, 305–313.
TS-EN-1015-11, (2013(. Methods of test for mortar for masonry-Part 11: determination of fexural and Compressice strength of hardened mortar. Anka-ra.
TS-EN-12504-4, (2012). Concrete tests-part 4: determination of ultrasonic pulsed wave velocity. Ankara.
TS-EN-196-1, 2016. Methods of testing cement - Part 1: Determination of strength. Ankara
Uğurlu, A., Karakoç, M. and Özcan, A., (2021). Effect of binder content and recycled concrete aggregate on freeze-thaw and sulfate resistance of GGBFS based geopolymer concretes. Construction and Building Materials, 301, 124246.
Xu, L.Y.,Alrefaei, Y., Wang, Y.S., Dai, J.G. (2021). Recent advances in molecular dynamiCS simulation of the N-A-S-H geopolymer system: Modeling, structural analysis, and dynamiCS. Construction and Building Materials, 276, 122196.
Yang, T., Gao, X., Zhang, J., Zhuang, X., Wang, H., and Zhang, Z. (2022). Sulphate resistance of one-part geopolymer synthesized by calcium carbide residue-sodium carbonate-activation of slag. Composites Part B: Engineering, 242, 110024
Ye, H., Chen, Z. and Huang, L., (2019). Mechanism of sulfate attack on alkali-activated slag: The role of activator composition. Cement and Concrete Research, 125,105868.
Yehualaw, M., Hwang, C.-L., Vo, D.-H. and Koyenga, A., (2021). Effect of alkali activator concentration on waste brick powder-based ecofriendly mortar cured at ambient temperature. Journal of Material Cycles and Waste Management.,23, 727–740.
Yu, Z., Ma, J., Sh,i H., Shen, X., Ye, G. (2016). Delayed ettringite formation in fy ash concrete under moist curing conditions. Internationa Conference Durability of Concrete Structure.
Zaidi, F. H. A., Ahmad, R., Abdullah, M. M. A. B., Abd Rahim, S. Z., Yahya, Z., Li, L. Y., and Ediati, R. (2021). Geopolymer as underwater concreting material: A review. Construction and Building Materials, 291, 123276.
Zhang, C., Wei, M., Hu, Z., Yang, T., Jiao, B., Zhu, H., ... and Lv, H. (2022). Sulphate resistance of silane coupling agent reinforced metakaolin geopoly-mer composites. CeramiCS International, 48(17), 25254-25266.
Zhao, N., Wang, S., Quan, X., Xu, F., Liu, K., and Liu, Y. (2021). Behavior of polyvinyl alcohol fiber reinforced geopolymer composites under the coupled attack of sulfate and freeze-thaw in a marine environment. Ocean Engineering, 238, 109734.
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